Oxidative coupling of methane over supported oxides promoted with alkali metals
✍ Scribed by Baronetti, G. T. ;Lazzari, E. ;García, E. Y. ;Castro, A. A. ;García Fierro, J. L. ;Scelza, O. A.
- Book ID
- 112682487
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 179 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0133-1736
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## CaO catalysts promoted with various elements were examined systematplly for the oxidative coupling of methane. 10 mol% Li+-CaO and 10 mol% Ba -CaO gave high C2 yield (23 to 26% at 1023 to 1073 K for 10% Li+-CaO) under CH4 and 02 partral pressure of 2.8 an $+1.4 kPa respectively. A three compo
A transient method to study the role of the different oxygen species involved in oxidative coupling of methane is discussed. The method is applied to two new active catalysts for this process, which are based on alkali metal loaded titanates of lanthanum and nickel and also to a lithium/titania cata