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Oxidative coupling of ketone enolates by ferric chloride

✍ Scribed by Frazier, Rawls H.; Harlow, Richard L.


Book ID
121326160
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
514 KB
Volume
45
Category
Article
ISSN
0022-3263

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Reactions of organic anions, 173. Oxidat
✍ WrΓ³bel, Zbigniew ;M??kosza, MieczysΕ‚aw πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 354 KB

## Abstract Nitronate anions derived from primary and secondary nitroal‐kanes undergo cross‐coupling reactions with diethyl alkylmalonate anions in alcohol/DMF solution when treated with silver nitrate. A catalytic amount of chloride ions is necessary to promote selective reaction.