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Oxidative Coupling of Diaryldisulfides by MoCl5 to Thianthrenes

✍ Scribed by Anke Spurg; Gregor Schnakenburg; Siegfried R. Waldvogel

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
299 KB
Volume
15
Category
Article
ISSN
0947-6539

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📜 SIMILAR VOLUMES

Oxidative Coupling Reactions Mediated by
Oxidative Coupling Reactions Mediated by MoCl5 Leading to 2,2′-Cyclolignans: The Specific Role of HCl
✍ Beate Kramer; Roland Fröhlich; Siegfried R. Waldvogel 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB

## Abstract The scope and performance of oxidative coupling reaction using MoCl~5~ can be significantly improved by employing Lewis‐acidic additives such as TiCl~4~, SnCl~4~, or SiCl~4~. Since the by‐product, HCl, plays a particular function as an inhibitor for MoCl~5~ by forming chloro complexes,