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Oxidative Coupling of Alkylated Anisole Derivatives Using MoCl5.

✍ Scribed by Daniela Mirk; Birgit Wibbeling; Roland Froehlich; Siegfried R. Waldvogel


Publisher
John Wiley and Sons
Year
2005
Weight
19 KB
Volume
36
Category
Article
ISSN
0931-7597

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Oxidative Coupling Reactions Mediated by
✍ Beate Kramer; Roland FrΓΆhlich; SiegfriedΒ R. Waldvogel πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 175 KB

## Abstract The scope and performance of oxidative coupling reaction using MoCl~5~ can be significantly improved by employing Lewis‐acidic additives such as TiCl~4~, SnCl~4~, or SiCl~4~. Since the by‐product, HCl, plays a particular function as an inhibitor for MoCl~5~ by forming chloro complexes,