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Oxidative Coupling Copolycondensation of 2,6-Dimethylphenol with 2,5-Dimethylphenol: Highly Thermostable Poly(phenylene ether)

โœ Scribed by Shibasaki, Yuji; Hoshi, Kenta; Suzuki, Eiichi; Shiraishi, Yutaka; Norisue, Yasumasa; Oishi, Yoshiyuki

Book ID
111777276
Publisher
Nature Publishing Group
Year
2009
Tongue
English
Weight
281 KB
Volume
41
Category
Article
ISSN
0032-3896

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Synthesis of ฮฑ,ฯ‰-bis(2,6-dimethylphenol)-poly(2,6-dimethyl-1,4-phenylene oxide) by phase transfer catalyzed polymerization of 4-bromo-2,6-dimethylphenol in the presence of 2,2-di(4-hydroxy-3,5-dimethylphenyl)propane
โœ Virgil Percec; James H. Wang ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Springer ๐ŸŒ English โš– 394 KB

~,o)-Bis(2,6-dimethylphenol)-poly(2,6-dimethyl-1,4-phenylene oxide) (PPO-2OH) was synthesized by the radical-cation phase transfer catalyzed polymerization of 4-bromo-2,6-dimethylphenol (1) in the presence of 2,2-di(4-hydroxy-3,5-dimethylphenyl)propane (2). Copolymerization experiments were performe