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Oxidative Coupling as a Biomimetic Approach to the Synthesis of Scytonemin

✍ Scribed by Ekebergh, Andreas; Karlsson, Isabella; Mete, Rudi; Pan, Ye; Börje, Anna; Mårtensson, Jerker


Book ID
118121248
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
809 KB
Volume
13
Category
Article
ISSN
1523-7060

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The first synthesis of mastigophorenes A and B by oxidative phenolic coupling of partially protected derivatives of their joint natural monomeric half, herbertenediol, is described. The synthesis starts from this diol itself or from the corresponding aldehyde, both available by isolation from the li