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Oxidative Cleavage of Functionalized Cyclic Olefins with H 2 O 2 Using a Peroxotungstate Complex

✍ Scribed by Ford, Mark J.; Kohlhepp, Helmut; Miller, Stephen; Riess, Sven; Schmidt, Jan Peter; Wisplinghoff, Lothar


Book ID
120327460
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
732 KB
Volume
15
Category
Article
ISSN
1083-6160

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A series of Zr based catalysts were synthesized using tetraneopentylzirconium as precursor complex and a silica partially dehydroxylated. Modifications of the Zr coordination sphere of the anchored complex, (=SiO)ZrNp, (Np = neopentyl), by hydrolysis or hydrogenolysis lead to catalysts showing unexp