✦ LIBER ✦

Oxidative cationic cyclization reactions effected by pyridinium chlorochromate

✍ Scribed by E.J. Corey; Dale L. Boger

Book ID: 104245825
Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 312 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)94800-2

No coin nor oath required. For personal study only.

✦ Synopsis

Pyridinium chlorochromate (PCC), C5H5NkClCr03, first introduced as an oxidizing reagent for alcohols just three years ago, 1 has found widespread use in organic synthesis. 2 In earlier work advantage was taken of the mildly acidic character of the reagent to bring about an essentially one-step conversion n (70% yield) of (-)-citronellol (l_) to (-)-pulegone (s), ' a useful reagent for asymmetric synthesis of prostaglandins. 4 The effectiveness of this synthesis together with our interest in exploring new techniques for

📜 SIMILAR VOLUMES

Novel oxidation of tetrasubstituted fura

Novel oxidation of tetrasubstituted furans by pyridinium chlorochromate

✍ Mohammed Shamim Akhtar; Manju Seth; Amiya Prasad Bhaduri 📂 Article 📅 1985 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 133 KB

Oxidation of Active Methylene Compounds

Oxidation of Active Methylene Compounds by Pyridinium Chlorochromate

✍ Bonadies, Francesco; Bonini, Carlo 📂 Article 📅 1988 🏛 Taylor and Francis Group 🌐 English ⚖ 230 KB

ChemInform Abstract: Pyridinium Chloroch

ChemInform Abstract: Pyridinium Chlorochromate Mediated Oxidative Cyclization of Sterically Crowded γ,δ-Unsaturated Alcohols.

✍ A. Srikrishna; B. Vasantha Lakshmi; A. V. S. Sudhakar 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 42 KB 👁 1 views

ChemInform Abstract: Microwave-Assisted

ChemInform Abstract: Microwave-Assisted Oxidation of Alcohols by Pyridinium Chlorochromate.

✍ Vaishali Chakraborty; Manobjyoti Bordoloi 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

Specific oxidative cleavage of allylic a

Specific oxidative cleavage of allylic and benzylic ethers by using pyridinium chlorochromate

✍ Janine Cossy; Samir Bouzbouz; Mohamed Lachgar; Abdelhak Hakiki; Badia Tabyaoui 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 180 KB

The oxidation of aikoxyaUylic ethers by PCC produces the corresponding ¢z,[J-unsaturated ketones or aldehydes and the oxidation of benzylic alcohols produces the corresponding ketones in satLrfltctory yields.

Oxidative cleavage of S-Arylmercaptoacet

Oxidative cleavage of S-Arylmercaptoacetic acids by pyridinium chlorochromate: Kinetic and correlation analysis

✍ S. Kabilan; R. Girija; V. Rajagopal 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 119 KB 👁 2 views

Kinetics of oxidation of 24 S-Arylmercaptoacetic acids (SAMA) by pyridinium chlorochromate (PCC) have been studied in acidmedium. The product of oxidation is the corresponding thiophenol. The rate data of meta-and para-substituted acids have been correlated well with I , R o values and the meta-comp