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Specific oxidative cleavage of allylic and benzylic ethers by using pyridinium chlorochromate

โœ Scribed by Janine Cossy; Samir Bouzbouz; Mohamed Lachgar; Abdelhak Hakiki; Badia Tabyaoui

Book ID
104258985
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
180 KB
Volume
39
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The oxidation of aikoxyaUylic ethers by PCC produces the corresponding ยขz,[J-unsaturated ketones or aldehydes and the oxidation of benzylic alcohols produces the corresponding ketones in satLrfltctory yields.

๐Ÿ“œ SIMILAR VOLUMES

Oxidative cleavage of S-Arylmercaptoacet
Oxidative cleavage of S-Arylmercaptoacetic acids by pyridinium chlorochromate: Kinetic and correlation analysis
โœ S. Kabilan; R. Girija; V. Rajagopal ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 119 KB ๐Ÿ‘ 2 views

Kinetics of oxidation of 24 S-Arylmercaptoacetic acids (SAMA) by pyridinium chlorochromate (PCC) have been studied in acidmedium. The product of oxidation is the corresponding thiophenol. The rate data of meta-and para-substituted acids have been correlated well with I , R o values and the meta-comp