Oxidative addition of dialkylphosphine oxides and of alkyl alkylphosphonites to iridium(I)
β Scribed by T.R.B. Mitchell
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 372 KB
- Volume
- 270
- Category
- Article
- ISSN
- 0022-328X
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## The addition reactions of diatomic molecules, X-Y (X-Y = HCl, HBr, HI, Cl? and BrJ to squareplanar d0 carborane-iridium(I) complexes of general formula trans-[Ir(o-carb)(CO)L,], where L = PPh3, PMePhz and carb = -2-R-1,2-and -7-R-I,7-BlO-CzHlo (R = H, CH,, CJI,) have been investigated in both the
IK(I)-and Rh(I)-complexes react with CF3-halides to give oxidative addition products. In the reaction of IrX(CO)(PEt3)2 with CF31, X = Cl, Br, I, and with CF3Br, X = Cl, Br, only the tram addition products are formed.
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