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Oxidations with Oxygen Difluoride

โœ Scribed by Merritt, Richard F.; Ruff, John K.

Book ID
125900381
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
414 KB
Volume
86
Category
Article
ISSN
0002-7863

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Perhaloalkyl Sulphuroxidifluoride imidesRNSOF3 (R = CF3-, C2F5-, i-C F 3 7-' CF3Cl-CF3-, CF2Br-CF2-) are isolated in high yield from the photochemical reaction of OF3 with the appropriate difluoride-imides. In all these reactions the difluoride-diimides R N = SF3 = N R are found as by-produc ZUSAMME