The oxidation of perhaloalkyl-sulphurdifluoride-imides by oxygen difluoride

✍ Scribed by I. Stahl; R. Mews; O. Glemser

• Book ID: 104150696
• Publisher: Elsevier Science
• Year: 1976
• Tongue: English
• Weight: 432 KB
• Volume: 7
• Category: Article
• ISSN: 0022-1139
• DOI: 10.1016/s0022-1139(00)83982-2

✦ Synopsis

Perhaloalkyl Sulphuroxidifluoride imidesRNSOF3 (R = CF3-, C2F5-, i-C F 3 7-' CF3Cl-CF3-, CF2Br-CF2-) are isolated in high yield from the photochemical reaction of OF3 with the appropriate difluoride-imides. In all these reactions the difluoride-diimides R N = SF3 = N R are found as by-produc ZUSAMMENFASSUNG Schwefeloxiddifluoridimide RNSOF3 (R= CF3-, C2F5-, i-C3F7-, CF3Cl-CF3-, CF3Br -CF3-) werden in hohen Ausbeuten aus der photoche-