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Oxidations of (R 3 tach)M(CO) 3 Complexes [M = Cr, Mo, W; R 3 tach = 1,3,5-Trialkyl-1,3,5-triazacyclohexane (R = t -Bu, Bn)]. Crystal Structures of ( t -Bu 3 tach)MO 3 ·15H 2 O (M = Mo, W)

✍ Scribed by Baker, Murray V.; North, Michael R.; Skelton, Brian W.; White, Allan H.

Book ID
126231000
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
155 KB
Volume
38
Category
Article
ISSN
0020-1669

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## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C