Oxidations and Transesterifications of Sugar Derivatives in Dimethyl Sulfoxide
β Scribed by Prof. Dr. G. Henseke; Dipl.-Chem. G. Hanisch
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- English
- Weight
- 104 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramineβT (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is β__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t
## Abstract __We study the structure and dynamics of hydrogenβbonded complexes of H~2~O/D~2~O and dimethyl sulfoxide (DMSO) by infrared spectroscopy, NMR spectroscopy and ab initio calculations. We find that single water molecules occur in two configurations. For one half of the water monomers both