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Simple and specific assay of penicillins by IR spectrophotometry in deuterium oxide and dimethyl sulfoxide solutions

✍ Scribed by Benito Casu; Paolo Ventura


Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
648 KB
Volume
63
Category
Article
ISSN
0022-3549

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## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t

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