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Oxidation—Reduction. III. The Kinetics of the Reduction of Sodium Anthraquinone β-Sulfonate by Titanous Ion and the Oxidation by Iodine

✍ Scribed by Johnson, Carl E.; Winstein, S.

Book ID
126944264
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
638 KB
Volume
74
Category
Article
ISSN
0002-7863

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The kinetics of the reduction of methyl
The kinetics of the reduction of methyl viologen and 9,10-anthraquinone-2-sulfonate by the benzopinacol anion
✍ S. W. Bigger; R. A. Craig; F. Grieser; A. J. Rouch; J. Scheirs 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 278 KB

The reduction of methyl viologen (MV") and 9,lO-anthraquinone-2-sulfonate (AQS) hy the henzopinacol anion in 50% (v/v) propan-2-ol/water was investigated spectroscopically. The rate constants for these reactions were found to be 12.9 ? 0.2 and 0.23 ? 0.01 M-' s-', respectively.