𝔖 Bobbio Scriptorium
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Oxidation von 1,3-Cyclohexadien mit PdCl2 und verschiedene Säuren

✍ Scribed by Doz. Dr. Spyridon Paraskewas


Publisher
John Wiley and Sons
Year
1977
Tongue
German
Weight
129 KB
Volume
49
Category
Article
ISSN
0009-286X

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Racemic 3‐amino‐1,2‐propanediol was selectively __N__‐acylated by several Z (__S__)‐amino acids using 1,1′‐carbonyldiimidazole as coupling reagent and tetrahydrofuran as solvent. In some cases (alanine, valine, phenylalanine) one of the two diastereomeric amides formed precipitates spontaneously and