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Oxidation-reduction of Pb2Sr2Ln1-xMxCu3-yAgyO8+.delta.

✍ Scribed by Gallagher, Patrick K.; O'Bryan, H. M.; Cava, R. J.; James, A. C. W. P.; Murphy, D. W.; Rhodes, W. W.; Krajewski, J. J.; Peck, W. F.; Waszczak, J. V.


Book ID
126472026
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
930 KB
Volume
1
Category
Article
ISSN
0897-4756

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Pb2Sr2Ceo.sCao.sCu30 s and Pb2Sr2Lnl\_xCaxCu308 with Ln =Pr, Tb and x= 0.0 and 0.5 have been studied by rare-earth L ILm edge XANES spectroscopy. The spectra of Pb 2 Sr2Ceo.sCao.sCu 308 show that Ca doping of Pb 2 Sr2CeCu 308 causes a partial oxidation of Ce. Analysis within the framework of the And