Oxidation Reactivity of Bis(μ-oxo) Dinickel(III) Complexes: Arene Hydroxylation of the Supporting Ligand
✍ Scribed by Kaoru Honda; Jaeheung Cho; Takahiro Matsumoto; Jungyun Roh; Hideki Furutachi; Takehiko Tosha; Minoru Kubo; Shuhei Fujinami; Takashi Ogura; Teizo Kitagawa; Masatatsu Suzuki
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 329 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0044-8249
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Aliphatic CÀH bond functionalization by various metalactive oxygen species M m /O n such as superoxo, peroxo, highvalent oxo-metal complexes, etc. is of great importance for understanding the reaction mechanisms of metalloenzymes and utilizing metal complexes as oxidation catalysts. [1][2][3][4] In
## Abstract A comparative kinetic study of the reactions of two mixed valence manganese(III,IV) complexes with macrocyclic ligands, [L^1^Mn^IV^(O)~2~Mn^III^L^1^], **1** (L^1^ = 1,4,7,10‐tetraazacyclododecane) and [L^2^Mn^IV^(O)~2~Mn^III^L^2^], **2** (L^2^ = 1,4,8,11‐tetraazacyclotetradecane) with 2