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A Bis(μ-alkylperoxo)dinickel(II) Complex as a Reaction Intermediate for the Oxidation of the Methyl Groups of the Me2-tpa Ligand to Carboxylate and Alkoxide Ligands

✍ Scribed by Jaeheung Cho; Hideki Furutachi; Shuhei Fujinami; Masatatsu Suzuki

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
136 KB
Volume
116
Category
Article
ISSN
0044-8249

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A Bis(μ-alkylperoxo)dinickel(II) Complex
A Bis(μ-alkylperoxo)dinickel(II) Complex as a Reaction Intermediate for the Oxidation of the Methyl Groups of the Me2-tpa Ligand to Carboxylate and Alkoxide Ligands
✍ Jaeheung Cho; Hideki Furutachi; Shuhei Fujinami; Masatatsu Suzuki 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB

Aliphatic CÀH bond functionalization by various metalactive oxygen species M m /O n such as superoxo, peroxo, highvalent oxo-metal complexes, etc. is of great importance for understanding the reaction mechanisms of metalloenzymes and utilizing metal complexes as oxidation catalysts. [1][2][3][4] In