A Mononuclear Alkylperoxocopper(II) Complex as a Reaction Intermediate in the Oxidation of the Methyl Group of the Supporting Ligand
β Scribed by Masayasu Mizuno; Kaoru Honda; Jaeheung Cho; Hideki Furutachi; Takehiko Tosha; Takahiro Matsumoto; Shuhei Fujinami; Teizo Kitagawa; Masatatsu Suzuki
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 138 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
Aliphatic CΓH bond functionalization by various metalactive oxygen species M m /O n such as superoxo, peroxo, highvalent oxo-metal complexes, etc. is of great importance for understanding the reaction mechanisms of metalloenzymes and utilizing metal complexes as oxidation catalysts. [1][2][3][4] In
The primary photoreactions due to charge transfer excitation of d 8 transition metal complexes of [MP 2 (N 3 ) 2 ] constitution (P 2 : mono-or diphosphane ligands) are strongly influenced by the central ion. While [MP 2 (N 3 ) 2 ] complexes of both palladium(II) and platinum(II) yield primarily the
the radical oxy-Cope rearrangement. [17] For this purpose, the sulfoxide 10 was prepared from norbornenone 8 via the allylic alcohol 9 (the direct synthesis with the procedure of Evans et al. does not work in this particular case). By treating the sulfoxide 10 with Bu 3 SnH and azobisisobutyronitril