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Oxidation of Unsaturated Hydrocarbons by Pd(O-Ac)2 Using a Molybdovanadophosphate/Dioxygen System

โœ Scribed by Takahiro Yokota; Satoshi Sakaguchi; Yasutaka Ishii

Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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Selective Wacker-type oxidation of termi
Selective Wacker-type oxidation of terminal alkenes and dienes using the Pd(II)/molybdovanadophosphate (NPMoV)/O2 system
โœ Takahiro Yokota; Aki Sakakura; Masayuki Tani; Satoshi Sakaguchi; Yasutaka Ishii ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 117 KB

Selective Wacker-type oxidation of long-chain terminal alkenes to methylketones was successfully achieved by using Pd(OAc) 2 /molybdovanadophosphate (NPMoV)/O 2 system. The selectivity of the reaction increased by slow addition of the alkenes to the catalytic solution. The oxidation of a,v-dienes wa