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Oxidation of transition metals in the liquid phase. 9. Direct synthesis and X-ray structural examination of complexes [(Me2S)AuBr] and [(Me2S)AuBr3]

✍ Scribed by G. A. Nifontova; O. N. Krasochkat; I. P. Lavrent'ev; D. D. Makitova; L. O. Atovmyan; M. L. Khidekel


Book ID
112447156
Publisher
Springer
Year
1988
Tongue
English
Weight
419 KB
Volume
37
Category
Article
ISSN
1573-9171

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Complexes with Dative Bonds between d- a
✍ Holger Braunschweig; Katrin Gruss; Krzysztof Radacki πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 289 KB

## Abstract **A platinum–beryllium adduct** (see structure) was prepared by the reaction of [Pt(PCy~3~)~2~] and BeCl~2~. Treatment with methyllithium resulted in ligand substitution at the beryllium center. Both complexes were structurally characterized and display unprecedented two‐center two‐elec