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Oxidation of Toluidine Blue by Chlorite in Acid and Mechanisms of the Uncatalyzed and Ru(III)-Catalyzed Reactions: A Kinetic Approach

โœ Scribed by Jonnalagadda, Sreekanth B.; Pare, Brijesh K.


Book ID
120187722
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
288 KB
Volume
114
Category
Article
ISSN
1089-5639

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Ru(III)-catalyzed oxidation of cysteine
โœ R. Chaturvedi; K. K. Mishra ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 101 KB

## Abstract Cysteine hydrochloride and methylene blue (MB) interact in a molar ratio of 2:1 in acidic medium forming cystine and dihydromethylene blue, and the reaction is catalyzed by Ru(III). At low concentrations (ca. 2.0 ร— 10^โˆ’8^ M), Cu(II) does not catalyze the reaction significantly but at th