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Oxidation of Threonylmethionine by Peroxynitrite. Quantification of the One-Electron Transfer Pathway by Comparison to One-Electron Photooxidation

✍ Scribed by Jensen, Jana L.; Miller, Brian L.; Zhang, Xiaoping; Hug, Gordon L.; Schöneich, Christian

Book ID
126182917
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
335 KB
Volume
119
Category
Article
ISSN
0002-7863

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The kinetics of NADH oxidation by 3 Dawson-type mixed heteropolyanions were studied in buffered aqueous pH = 7 medium, by the stopped flow technique and UV-visible spectroscopy. The log of k was a linear function of the E ° of the first redox systems of the heteropolyanions with a slope of 16.5 V-1