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One electron oxidation of benzyltrialkylsilanes catalysed by lignin peroxidase: comparison with the oxidation induced by chemical oxidants

✍ Scribed by Maria Francesca Gerini; Osvaldo Lanzalunga

Book ID
117053581
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
117 KB
Volume
303
Category
Article
ISSN
0006-291X

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✍ Enrico Baciocchi; M.Β Francesca Gerini; Osvaldo Lanzalunga; Andrea Lapi; MariaΒ Gr πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 270 KB πŸ‘ 2 views

Lignin peroxidase catalyses the oxidative N-demethylation of ring-substituted N,N-dimethylanilines by an electrontransfer mechanism whereby an anilinium radical cation is formed which is then deprotonated by the enzyme. Information on the nature of the basic centre which deprotonates the radical cat