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Oxidation of Thiols with Dinitrogen Tetroxide

✍ Scribed by Kramer, Thomas; Röder, Thorsten

Book ID
118118395
Publisher
Taylor and Francis Group
Year
2004
Tongue
English
Weight
154 KB
Volume
34
Category
Article
ISSN
0039-7911

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📜 SIMILAR VOLUMES

New selective oxidation of thiols to the
New selective oxidation of thiols to the corresponding thiolsulfonates with dinitrogen tetroxide: one pot syntheses of thiolsulfonates from thiols
✍ Yong H. Kim; Kōichi Shinhama; Daikichi Fukushima; Shigeru Oae 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 129 KB

We have recently reported that thereactionsof thiols with an equimolar amount of N204 readily afford the thionitrites quantitatively 1) . We have now found that the both aromatic and alkyl thiols reacted readily with excess N204 at low temperatures(ca. -20°C) thiolsulfonates in good yields. RSH 1 RS