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Oxidation of Thiols with Dinitrogen Tetroxide.

✍ Scribed by Thomas Kramer; Thorsten Roeder


Publisher
John Wiley and Sons
Year
2004
Weight
87 KB
Volume
35
Category
Article
ISSN
0931-7597

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The Behaviors of Metal Acetylides with D
✍ Christopherβ€…J. Woltermann; Harold Shechter πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 158 KB

Lithium phenylacetylide (1a) and N 2 O 4 (2) at Γ€ 788 yield diphenylbutadiyne (6a) by oxidative coupling, phenylacetylene (7a) by oxidation and then solvent H-abstraction, and benzoyl cyanide (8) by dimerizativerearrangement of nitroso(phenyl)acetylene (23). Nitro(phenyl)acetylene (3, R Ph) is not o