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Oxidation of the Natural Amino Acids by a Ferryl Complex: Kinetic and Mechanistic Studies with Peptide Model Compounds

✍ Scribed by Abouelatta, Ahmed I.; Campanali, Ashley A.; Ekkati, Anil R.; Shamoun, Mark; Kalapugama, Suneth; Kodanko, Jeremy J.

Book ID: 120259418
Publisher: American Chemical Society
Year: 2009
Tongue: English
Weight: 998 KB
Volume: 48
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic900527c

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## Abstract The kinetics of oxidation of indole‐3‐acetic acid (IAA) by peroxodisulfate (PDS) has been carried out in aqueous acetic acid medium. First‐order dependence of rate each with respect to [IAA] and [PDS] was observed. The reaction rate was unaffected by added [H^+^]. Increase of percentage