Oxidation of the iron(II) complex with 3,5-dimethylpyrazole by air in acetonitrile and dibenzyl ether
β Scribed by E. V. Perova; S. E. Nefedov; D. G. Chikhichin; G. L. Kamalov
- Book ID
- 110182458
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2009
- Tongue
- English
- Weight
- 291 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0036-0236
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The use of non-aqueous solvents is a modern trend in titrimetric analysis. Acetonitrile especially seems to be a very promising medium for acid-bane titrations as well as for redox titrations. In connection with tile latter category, investigations with cerium(IV) 1, iron(III) 2 and copper(II)3-5 sh
The oxidative cyclization of 5-(2-amino-5-methoxycarbonylphenyl)-substituted tricarbonyl[h 4 -cyclohexa-1,3-diene]iron complexes by air in protic medium provides the corresponding tricarbonyl[h 4 -4a,9a-dihydro-9H-carbazole]iron complexes. This procedure is applied to the total synthesis of the 3-me