The use of non-aqueous solvents is a modern trend in titrimetric analysis. Acetonitrile especially seems to be a very promising medium for acid-bane titrations as well as for redox titrations. In connection with tile latter category, investigations with cerium(IV) 1, iron(III) 2 and copper(II)3-5 sh
✦ LIBER ✦
Kinetic data on the oxidation of 1,1-diphenyl-2-picrylhydrazyl by copper(II) and iron(III) perchlorates, and by ammonium hexanitratocerate(IV) in anhydrous acetonitrile
✍ Scribed by I. Němec; H.L. Kies; I. Němcová
- Book ID
- 108305224
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 531 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0003-2670
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## Abstract A comparative kinetic study of the reactions of two mixed valence manganese(III,IV) complexes with macrocyclic ligands, [L^1^Mn^IV^(O)~2~Mn^III^L^1^], **1** (L^1^ = 1,4,7,10‐tetraazacyclododecane) and [L^2^Mn^IV^(O)~2~Mn^III^L^2^], **2** (L^2^ = 1,4,8,11‐tetraazacyclotetradecane) with 2