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Oxidation of steroidal ketones. VII. Cleavage of steroidal conjugated ketones with ruthenium tetroxide

✍ Scribed by Piatak, David M.; Bhat, H. B.; Caspi, Eliahu


Book ID
126318118
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
742 KB
Volume
34
Category
Article
ISSN
0022-3263

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The ruthenium tetroxide oxidation of ste
✍ W.J. Rodewald; Z. BoΕ„cza-Tomaszewski πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 217 KB

During our investigations on sgntheaie of heterocyolic eteroids the problem of degradation of conjugated homoannular dlenee by oxidatlve cleavage of olefinic bond8 arose. Rutlmenlum tetroxide was found to be a good oxidant for degradation of steroidal oonjugated ketones and aromatic steroids 'e2). T