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Oxidation of Steroidal Ketones. III. Selenium Dioxide-Catalyzed Hydrogen Peroxide Oxidation of 4-En-3-ones 1

โœ Scribed by Caspi, E.; Balasubrahmanyam, S. N.


Book ID
120426666
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
531 KB
Volume
28
Category
Article
ISSN
0022-3263

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Oxidation of steroidal ketones I. Seleni
โœ E. Caspi; S.N. Balasubrahmanyam ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 159 KB

The selenium dioxide catalyzed reaction of hydrogen peroxide with saturated cyclic ketones has been shown to lead to carboxylic acids with a contracted ring. 2,3 We have investigated this reaction for steroidal 3-ketones of 5a and 58 series. In our hands the major reaction was not ring contraction b