๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Oxidation of steroidal ketones II selenium dioxide catalyzed hydrogen peroxide oxidation of 4-en-3-ones

โœ Scribed by E. Caspi; S. N. Balasubrahmanyam

Book ID
112709808
Publisher
Springer
Year
1963
Tongue
English
Weight
272 KB
Volume
19
Category
Article
ISSN
1420-682X

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Oxidation of steroidal ketones I. Seleni
Oxidation of steroidal ketones I. Selenium dioxide catalyzed hydrogen peroxide oxidation of ring a saturated 3-ketones
โœ E. Caspi; S.N. Balasubrahmanyam ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 159 KB

The selenium dioxide catalyzed reaction of hydrogen peroxide with saturated cyclic ketones has been shown to lead to carboxylic acids with a contracted ring. 2,3 We have investigated this reaction for steroidal 3-ketones of 5a and 58 series. In our hands the major reaction was not ring contraction b

Cobalt(II)-catalyzed oxidation of alcoho
Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide
โœ Subhabrata Das; T. Punniyamurthy ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 317 KB

The oxidation of aliphatic and aromatic alcohols into the corresponding carboxylic acid analogues and ketones has been carried out using 30% H 2 O 2 and cobalt(II) complex 1 in good to high yields. The reaction is safe, clean and functions in the absence of additives.