Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide
โ Scribed by Subhabrata Das; T. Punniyamurthy
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 317 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
The oxidation of aliphatic and aromatic alcohols into the corresponding carboxylic acid analogues and ketones has been carried out using 30% H 2 O 2 and cobalt(II) complex 1 in good to high yields. The reaction is safe, clean and functions in the absence of additives.
๐ SIMILAR VOLUMES
A variety of aromatic and some aliphatic aldehydes are efficientlv transformed to the corresvondinq carboxvlic acid in presence of catalytic amount of Cobal: (II)-chloride, molecular oxyyen and acetic anhydride at room temperature. Phenolic aldehydes underyo acylatiue oxidation to give the correspon