Manganese(II) is oxidized by ozone in acid solution, k ϭ (1.5 Ϯ 0.2) ϫ in HClO 4 and in H 2 SO 4 . The plausible mechanism is 3 Ϫ1 Ϫ1 3 Ϫ 1 Ϫ 1 10 M s k ϭ (1.8 Ϯ 0.2) ϫ 10 M s an oxygen atom transfer from O 3 to producing the manganyl ion which subse-2ϩ 2ϩ Mn MnO , quently reacts rapidly with to for
✦ LIBER ✦
Oxidation of propane-1,2-diol by acidic manganese(V) and manganese(VI)
✍ Scribed by Éva Záhonyi-Budó; LászlóI. Simándi
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 348 KB
- Volume
- 248
- Category
- Article
- ISSN
- 0020-1693
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