Oxidation of indoleacetic acid by 1,10-phenanthroline—manganese complexes
✍ Scribed by Russell Pressey
- Publisher
- Elsevier Science
- Year
- 1991
- Weight
- 235 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0304-5102
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The kinetics of the oxidation of 1,10-phenanthroline (1,10-phen) by permanganate were investigated in alkaline medium. A first-order, fractional-order and zero-order dependence of the rate each in [MnO 4 À ], [1,10-phen] and [OH À ], respectively, was observed. The data suggest that the oxidation pr
## Abstract The kinetics of oxidation of several substituted quinols by a series of Tris(1,10‐phenanthroline)iron(III) complexes has been investigated with a stopped‐flow technique at 6.0 and 20.0°C. The reactions were found to be first order on both reactants and independent of acidity. The second