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Oxidation of p-hydroxymethylbenzoatopenta-amminecobalt(III) by one-electron oxidizing agents

โœ Scribed by Robson, Richard.; Taube, Henry.


Book ID
126091853
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
977 KB
Volume
89
Category
Article
ISSN
0002-7863

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One electron oxidizing agents have been employed to achieve the isomerization of epoxides to ketones.The reactions most likely proceed via a radical cation chain electron-transfer mechanism. Recently, the electrochemical conversion of epoxides to ketones,ls2 a procedure more convenient than