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Electron-transfer chain isomerization of epoxides induced by one-electron oxidizing agents

✍ Scribed by Luigi Lopez; Luigino Troisi

Book ID
104229564
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
280 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

One electron oxidizing agents have been employed to achieve the isomerization of epoxides to ketones.The reactions most likely proceed via a radical cation chain electron-transfer mechanism.

Recently, the electrochemical conversion of epoxides to ketones,ls2 a procedure more convenient than

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Cyclobutadiene to tetrahedrane: Valence
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## Abstract A new procedure for synthesizing tetrakis(trimethylsilyl)tetrahedrane from tetrakis(trimethylsilyl)cyclobutadiene is reported. Valence isomerization of cyclobutadiene to tetrahedrane induced by one‐electron oxidation has been developed by the addition of tris(pentafluorophenyl)borane as