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Oxidation of olefins by palladium(II). 13. Product distribution and kinetics of the oxidation of 2-cyclohexenol and 2-cyclohexenol-1-d by PdCl42- in aqueous solution

โœ Scribed by Zaw, Kyaw; Henry, Patrick M.

Book ID
126942129
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
813 KB
Volume
11
Category
Article
ISSN
0276-7333

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๐Ÿ“œ SIMILAR VOLUMES

Oxidation of olefins by palladium(II). P
Oxidation of olefins by palladium(II). Part XIV. Product distribution and kinetics of the oxidation of ethene by PdCl3 (pyridine)โˆ’ in aqueous solution in the presence and absence of CuCl2: a modified Wacker catalyst with altered reactivity
โœ John W. Francis; Patrick M. Henry ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 899 KB

In the absence of CuC12, ethene was oxidized to ethanal by PdCl,(pyridine) -in aqueous solution by the rate expression: \* where K' is the equilibrium constant for n-complex formation between ethene and PdCl,(Py) -(Py =pyridine). This rate expression is of the same form as that previously found for