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Oxidation of olefins by palladium(II). 12. Product distributions and kinetics of the oxidation of 3-buten-2-ol and 2-buten-1-ol by tetrachloropalladate (PdCl42-) in aqueous solution

โœ Scribed by Zaw, Kyaw; Henry, Patrick M.


Book ID
126424864
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
775 KB
Volume
55
Category
Article
ISSN
0022-3263

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Oxidation of olefins by palladium(II). P
โœ John W. Francis; Patrick M. Henry ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 899 KB

In the absence of CuC12, ethene was oxidized to ethanal by PdCl,(pyridine) -in aqueous solution by the rate expression: \* where K' is the equilibrium constant for n-complex formation between ethene and PdCl,(Py) -(Py =pyridine). This rate expression is of the same form as that previously found for