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Oxidation of methyl linoleate in micellar solutions induced by the combination of iron(II)/ascorbic acid and iron(II)/H2O2

✍ Scribed by Fabrizio Miccichè; Jacco van Haveren; Eef Oostveen; Jozua Laven; Weihua Ming; Zahit Okan Oyman; Rob van der Linde

Book ID
116177448
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
338 KB
Volume
443
Category
Article
ISSN
0003-9861

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On the oxidation of saturated hydrocarbo
On the oxidation of saturated hydrocarbons with H2O2 in the presence of iron(II)-picolinate or iron(II)−1,10 phenanthroline 2-carboxylate.
✍ G. Balavoine; D.H.R. Barton; J. Boivin; A. Gref 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 261 KB

A new catalytic system for highly selective oxidation of saturated hydrocarbons into ketones is described. This system is based on the combination offerrous picolinate (or l,lOphenanthroline 2-carboqylate) and H202 in pyridine sohuion.Under these conditions cyclohexane gave mabdy cyclohmanone (90% ,