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Oxidation of lipids. XI. Spin trapping and identification of peroxy and alkoxy radicals of methyl linoleate

✍ Scribed by Teruaki Yamada; Etsuo Niki; Seiichi Yokoi; Jyunichi Tsuchiya; Yorihiro Yamamoto; Yoshio Kamiya


Book ID
107737052
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
285 KB
Volume
36
Category
Article
ISSN
0009-3084

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The difficulties inherent in characterising reactive free radicals by electron spin resonance can often be avoided by the use of a 'spin trapping' technique. The method is based on the conversion of transient radicals to long-lived paramagnetic species by their addition to a diamagnetic scavenger,

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## Radicals generated in linoleic acid and deuterated linoleic acid have been trapped by the spin trap 2-methyl-2-nitroso-propane & q % i = z = 7 GOOH +N-b (MNP) and identified by electron spin resonance (ESR) and ENDOR spectroscopy. The formation of two distinct secondary alkyl radical adducts (o