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Oxidation of hydrocarbons of the monoarylmethane series by oxygen in a basic medium

✍ Scribed by G. A. Artamkina; A. A. Grinfel'd; I. P. Beletskaya


Book ID
112445157
Publisher
Springer
Year
1984
Tongue
English
Weight
701 KB
Volume
33
Category
Article
ISSN
1573-9171

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Kinetics and mechanism of sulfite oxidat
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## Abstract The kinetics of the permanganate‐sulfite redox reaction has been studied in the alkaline medium using a stopped‐flow technique. In the pH range 10 to 12 the reaction was found to obey the rate expression: βˆ’Β½__d__[MnO~4~^βˆ’^]/__dt__ = (__k__~1~ + __k__~2~[OH^βˆ’^]) [MnO~4~^βˆ’^] [SO~3~^2βˆ’^].