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Oxidation of Hydrocarbons by [(phen) 2 Mn(μ-O) 2 Mn(phen) 2 ] 3+ via Hydrogen Atom Abstraction

✍ Scribed by Wang, Kun; Mayer, James M.


Book ID
125892871
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
302 KB
Volume
119
Category
Article
ISSN
0002-7863

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✍ Ganti Swarnabala; K. Rajender Reddy; Jyotsna Tirunagar; Melath V. Rajasekharan 📂 Article 📅 1994 🏛 Springer 🌐 English ⚖ 321 KB

The crystal and molecular structures of [Mn(phen)-(OHz)C13] (1) and [Mn(acac)2(OHE)/]C104"2H20 (2) were determined. A comparison is made of the Jahn-Teller distortion in these compounds with those observed in other manganese(III) complexes with monodentate axial ligands.