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Oxidation of hydrazine IX. Mono- and di-delectronation of hydrazine by permanganate in hydrochloric acid solution

✍ Scribed by Houpt, A. G.; Sherk, K. W.; Browne, A. W.

Book ID: 126969336
Publisher: American Chemical Society
Year: 1935
Weight: 523 KB
Volume: 7
Category: Article
ISSN: 0096-4484
DOI: 10.1021/ac50093a027

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The copper-catalyzed oxidation of hydrazine by iron(II1) in acid solution follows the rate law -d[Fe(III)]/dt = ~K~[CU(II)]~/(K~ + [H+]), where Kh is the hydrolysis constant of Cu2+, k was found t o be 8.8f0.8, 13.2f1.4 and 17.5f1.3 min-' at 35, 40, and 45OC respectively and p= 0.2 mol/L. The compos