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Oxidation of Dimethyl Sulfoxide in Aqueous Solution Using Microbubbles

✍ Scribed by Li, Pan; Tsuge, Hideki; Itoh, Keiko


Book ID
120342109
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
430 KB
Volume
48
Category
Article
ISSN
0888-5885

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## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t