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Detection of Oxidation of L-Cysteine by Dimethyl Sulfoxide in Aqueous Solutions by IR Spectroscopy

✍ Scribed by Papanyan, Z.; Markarian, S.

Book ID
121603544
Publisher
Springer US
Year
2013
Tongue
English
Weight
513 KB
Volume
80
Category
Article
ISSN
0021-9037

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πŸ“œ SIMILAR VOLUMES

Kinetics and mechanism of oxidation of d
Kinetics and mechanism of oxidation of dimethyl sulfoxide by chloramine-T in aqueous solution
✍ D. S. Mahadevappa; M. B. Jadhav; H. M. K. Naidu πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 569 KB

## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t