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Oxidation of Cu(I) by oxygen in concentrated NaCl solutions—II. Kinetics in a known interfacial area cell

✍ Scribed by A. Gaunand; N. Papassiopi

Book ID
107730098
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
554 KB
Volume
40
Category
Article
ISSN
0009-2509

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Oxidation of Cu(I) by oxygen in concentr
Oxidation of Cu(I) by oxygen in concentrated NaCl solutions—I. Homogeneous kinetics of oxidation by molecular oxygen in solution
✍ N. Papassiopi; A. Gaunand; H. Renon 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 497 KB

The homogeneous oxidation of cuprous chloride in 2 M NaCl solutions by dissolved molecular oxygen was studied, using a batch reactor, at constant pH and temperature. The rate of homogeneous reaction is represented by the expression: R = k[O,] [CU(I)]'.~ with k = 2.8 x 106cm4-5mol-' 's-l where square