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Oxidation of cobalt(II) amine complexes to mononuclear cobalt(III) complexes by dioxygen

โœ Scribed by Eaton, Donald R.; O'Reilly, Alex


Book ID
111962126
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
518 KB
Volume
26
Category
Article
ISSN
0020-1669

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New alkenylcobalt(III) complexes from ox
โœ Akira Nishinaga; Shigekazu Yamazaki; Teruo Matsuura ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 273 KB

Oxidation of hydrazones of aliphatic ketones by a Co(salen)dioxygen system in dichloromethane results in oxidative denitrogenation of the hydrazones to give new l-alkenylcobalt(I11) complexes. Treatment of the alkenyl complexes with sodium borohydride gives the corresponding cis-olefins. Oxygenation